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Mountain Blue

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Nevertheless, the specific saturation magnetization is reduced due to a dead magnetic layer at the surface of the particles [3] if the temperature and the time of annealing are decreased.
In the case of strontium ferrites, the influence of a strontium excess on the crystallografic structure is the same. The lattice occupation is not perturbed if an excess of strontium according to n = 5.25 is used. For a larger amount of strontium in the starting xerogel, the intermediate phase SrFe03., can be separated by etching with HC1. Nevertheless, in the range n = 5.25
6.0, the influence of the surplus on the static magnetic properties is typically different compared to intrinsic barium hexaferrites. Here, the specific saturation magnetization of the powders annealed at 950°C for 5h does not depend on the ratio n, whereas HCM decreases from 480 kA/m for n = 6.0 to 400 kA/m in the case of n = 5.25. This decrease of the coercive field strength for n < 6.0 can be avoided by reducing the annealing temperature to 850°C. According to the irreversible part of the
FMR-spectra in figure 2 (right) showing no shift of the high field resonance peak with decreasing annealing temperature, the effective anisotropy field strength of the samples is not influenced, whereas the transition from incoherent to coherent magnetization reversal, indicated by the height of the low field resonance peak, by reducing the annealing temperature is obvious. If the annealing time is decreased, the coercive field strength of strontium ferrite powders is above 500 kA/m.

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